Surface tension of electrolyte solutions: A self-consistent theory

OFFPRINT Surface tension of electrolyte solutions: A self-consistent theory

We study the surface tension of electrolyte solutions at the air/water and oil/water interfaces. Employing field-theoretical methods and considering short-range interactions of anions with the surface, we expand the Helmholtz free energy to first order in a loop expansion and calculate the excess surface tension. Our approach is self-consistent and yields an analytical prediction that reunites ...

Prediction of Surface Tension in Single and Mixed Electrolyte Solutions

Prediction of Surface Tension in Single and Mixed Electrolyte Solutions

In this study, the Langmuir adsorption isotherm has been coupled with activity coefficient models for prediction of surface tension of single and mixed electrolyte solutions. Various activity models such as Meissner, Pitzer and extended UNIQUAC have been used and coupled with Langmuir adsorption isotherm. The model parameters were determined through mathematical optimization using experimental ...

Interfacial Tension of Electrolyte Solutions

A theory is presented to account for the increase in surface tension of water in the presence of electrolyte. Unlike the original “grandcanonical” calculation of Onsager and Samaras, which relied on the Gibbs adsorption isotherm and lead to a result which could only be expressed as an infinite series, our approach is “canonical” and produces an analytic formula for the excess surface tension. F...

Surface tension and a self-consistent theory of soft composite solids with elastic inclusions.

The importance of surface tension effects is being recognized in the context of soft composite solids, where they are found to significantly affect the mechanical properties, such as the elastic response to an external stress. It has recently been discovered that Eshelby's inclusion theory breaks down when the inclusion size approaches the elastocapillary length L≡γ/E, where γ is the inclusion/...